Automatic apparatus for stripping deposited metal from a cathode plate in electrowinning process

ABSTRACT

Apparatus for stripping deposited metal from a cathode plate in an electrolytic metal winning process includes a plurality of operating stations. In one operating station, a cathode holder pivotally mounted on the cathode plate is pivoted from a position disposed over an edge portion of the cathode plate to a position exposing the edge portion. In another station, a preliminary stripping means having scraper elements is insertable between the cathode plate and the deposited metal at the edge portion to partially separate the deposited metal from the cathode plate. At a further station, a main stripping means having a scraper blade is insertable between the partially separated cathode plate and deposited metal and movable relative to the cathode plate and deposited metal to effect complete separation of the deposited metal from the cathode plate.

ite States Sekine et a1.

atent [1 1 AUTOMATIC APPARATUS FOR STRIPPING DEPOSITED METAL FROM A CATIIODE PLATE IN ELECTROWINNING PROCESS [75] Inventors: Kunio Sekine; Yukio Kamata;

Yoshio Yamaishi, all of Kosaka-machi, Japan [73] Assignee: The Dowa Mining Co., Ltd., Tokyo,

Japan [22] Filed: Oct. 26, 1972 [21] Appl. No.: 301,219

[52] US. Cl 204/198, 204/226, 204/281 [51] Int. Cl. B65g 49/00 [58] Field of Search 204/12, 281, 198, 226, 204/208; 156/584 [56] References Cited UNITED STATES PATENTS 3,689,396 9/1972 Casagrande et a1. 204/281 3,414,502 12/1968 Porrata et a1. 204/281 FOREIGN PATENTS OR APPLICATIONS 512,913 11/1930 Germany 204/12 Primary Examiner-T. M. Tufariello Attorney, Agent, or FirmToren, McGeady and Stanger [57] ABSTRACT Apparatus for stripping deposited metal from a cathode plate in an electrolytic metal winning process includes a plurality of operating stations. ln one operating station, a cathode holder pivotally mounted on the cathode plate is pivoted from aposition disposed over an edge portion of the cathode plate to a position exposing the edge portion. ln another station, a preliminary stripping means having scraper elements is insertable between the cathode plate and the deposited metal at the edge portion to partially separate the deposited metal from the cathode plate. At a further station, a main stripping means having a scraper blade is insertable between the partially separated cathode plate and deposited metal and movable relative to' the cathode plate and deposited metal to effect complete separation of the deposited metal from the cathode plate.

8 Claims, 12 Drawing Figures PATENTELHUV 1 21974 I SHEET 20F 5 FIGS FIGB' FIG.4.

AUTOMATIC APPARATUS FOR STRIPPING DEPOSITED METAL FROM A CATIIODE PLATE IN ELECTROWINNING PROCESS This invention relates to an automatic apparatus for stripping deposited metal, such as zinc, copper or the like, from cathode plates in an electrowinning process.

Since the dimensions of electrodes have become increasingly larger and automated electrolytic processes are required, attempts have been made automate the process of stripping deposited zinc from the surface of cathodes in lieu of the conventional and inefficient hand operation.

One object of the present invention is to provide an improved automatic stripping machine which operates more efficiently than known, existing machines.

Another object of this invention is to provide a metal stripping apparatus of the scraper type with which metal stripping can be carried out without any striking force or the like which would cause deformation of the cathode; plate and make noise.

A further object of this invention is to provide a metal stripping apparatus with which a reliable operation can be carried out regardless of the conditions of the deposit.

Other objects of the invention will be apparent hereinafter from the specification and from the recital of the appended claims, particularly when read in conjunction with the accompanying drawings.

In the drawings:

FIG. 1 is a side elevational view showing an automatic metal stripping apparatus constructed according to one embodiment of this invention.

FIG. 2 is a plan view of the apparatus shown in FIG. I.

FIG. 3 is a sectional view taken along the line -0 in FIG. I showing the feeder for carrying cathode plates.

FIG. 4 shows an elevation of a cathode plate. FIG. 5 is a side view of the cathode plate in FIG. 4.

FIG. 6 shows a section taken along the line S S in FIG. 3.

FIG. 7 is a side section view showing a lifting device for a movable cathode holder.

FIG. 8 is a vertical and front view of the device shown in FIG. 7.

FIG. 9 is a side view of a preliminary stripping device.

FIG. 10 is a plan view of the device in FIG. 9.

FIG. 11 is a side view of a main stripping device.

FIG. 12 is a plan view of the device in FIG. 11.

Referring now to the drawings and firstly to FIG. 3, a cathode plate 1 used according to this invention has a movable holder 2 and a set of conventional stationary edge strips 3. After an electrolytic operation is carried out in an electrolytic bath, the cathode plates are drawn up and washed, and then put on a conveyor 4. The movable holder 2 is made of electrically nonconductive and acid-proof material and has a groove 5 having one side opened in a square shaped configuration. The upper part of one side edge of the cathode plate 1 is clipped or received in the groove Sand the holder is attached to the cathode plate by means of pivot pin 6 (see FIG. 3). As shown in FIG. 6, the clipping portion 2a of the movable holder 2 has tapered faces 7 on the outer sides at which the groove '5 is opened. At the other side 8 the holder 2 has an enlarged portion 9 adapted to be engaged by a lifting arm of a movable holder lifter so that the movable holder can be turned and lifted.

Referring now to FIGS. I and 2, the conveyor 4 carries the cathode plate I by an intermittent movement to a station (a) from which a delivering device 10 moves the plate to a station (b) at which the cathode plate is put down on hanger plates 12 provided in a feeder II as shown in FIG. 3. Next, being supported on sliding rails I4, the cathode plate I is lifted by a cylinder 113. Then resting on the sliding rails mounted on sliding bearings 15 and their support plates I6, the cathode is moved by a transfer cylinder 17 to a station (0) at which it is again put down on the hanger plates 12 by the cylinder 13.

At the station (c) a lifting device 18 for the movable holder 2 is actuated tolift or turn the holder. As shown in FIGS. 7 and 8, in order that during the movement of the cathode plate, which is subject to force in the lateral direction, is accurately positioned, locking arms 19 are turned from a position as shown by a dot and dash line in FIG. 7 by actuation of a locking cylinder 20 (FIG. 2) through a shaft 21 (FIG. 7) to clamp a beam 1' of the cathode plate 1.

Firstly a bracket 24 is supported on a guide shaft 22 by means of bearings 23 in a position as shown by a dot and dash line in FIG. 7. When the transfer movement of the cathode is finished, the bracket 24 moves down by the action of a cylinder 25 in a vertical direction and stops at a positionat which the movable holder 2 can be lifted.

Next a cylinder 26 for lifting the holder is actuated to turn the lifting arms 32 upward by means of a transmission comprising a rack 27, a gear 28, a sprocket 29, a roller chain 30 and a sprocket 31. At that time the tips of the lifting arm 32 are engaged with the enlarged portion 9 of the movable holder 2 and pushes or turns the latter upwardly. During the turning movement the movable holder 2 pushes away a holder support 33 and lifted up to a position as shown by a dot and dash line in FIG. 7.

When the lifting movement ends, holder lifting cylinder 26 returns to move the holder lifting arm 32 to the initial position and successively the cylinder 25 moves vertically to return and to lift the bracket 24 to the initial position where it does not hinder the travel of the cathode plate 1.

The movable holder 2 in its lifted positionis supported by the holder support 33 retained by a spring 34 and is prevented from dropping. During the movementof the cathode plate 1 the holder 2 is carried on the guide rail 35 (FIGS. 8 and 9) to slide without dropping until it reaches the station (d) at which a preliminary stripping operation is carried out.

Electrodeposited metal 36 at its portion in which the movable holder 2 is lifted from the plate 1 is shownas deposited in a form that the end seam is separated outward from the plate.

When the cathode plate 1 arrives at the predetermined position, a beam l on the plate I is locked by lateral lockingmembers 37, 38 which are moved at the locking position by the action of, locking cylinders 20,

"39 respectively.

that a pair of scraper blades 41 is opened as shown by a dot and dash line (k) in FIG. 10.

When locking action of the cathode plate 1 is finished, the scraper blades 41 are turned and brought in contact with both faces of the plate 1 by the turning of an arm 43 which turning is actuated by a cylinder 42. Gear wheels 44 are provided which are synchronized with the turning of the blades 41. The head of the preliminary stripping device 40 supported by bearings 45 and guide rod 46, is advanced by a cylinder 47. The tips of the anti-abrasive scraper blades 41 are then inserted into a gap formed between deposited metal 36 and the cathode plate 1. When the blades enter into the gap a predetermined distance, the scraper blades are turned or pivoted apart from each other until they reach position (1). After the above mentioned cycle is completed completes each member or device returns to its initial position.

Upon opening of the scraper blades 41, the electro deposited metal is separated from the cathode plate to a great extent, but when the tips of the blades 41 leave or are withdrawn from the deposited metal, the deposited metal tends to return to the initial state or position by its own resiliency. However a certain gap is still maintained between the deposited metal and the cathode plate. Owing to this, after the preliminary stripping, the deposited metal is in a state in which it can be easily stripped off from the cathode plate 1 by a main scraper which operates at a following station.

It has been proved from actual operations that according to this invention the distance of separation between the stripped metal and the cathode plate is mm and that of the stripped part is longitudinally 200 300 mm at the scraper side and about one half of this at the counter side.

It has also been verified that if this preliminary treatment leads to a favorable partial stripping, the main stripping operation can be successfully carried out under the extremely improved conditions without abrasion and damage of the cathode plate by the tips of the main scraper.

The main scraper body does not directly contact the cathode plate so that the plate can be prevented from being mechanically damaged and the stripping operation can be smoothly carried out at high speed.

When the above-mentioned pretreatment ends, feeder 1 1 is actuated to bring the cathode plate 1 to the process for detecting the result of the preliminary stripping at the station (e).

In the detecting process an electrically or mechanically actuated detector 48 is operated to detect whether the preliminary stripping is completely carried out and to send a signal to the main stripping device 49.

As detection is finished, the cathode plate 1 is delivcred by the feeder 11 to the main stripping device at the station (f).

As clearly shown in FIGS. 11 and 12, the main stripping device 49 has a scraper 50 having tips which are retracted to the position (m) during the travelling of the cathode plate 1. When the cathode plate 1 reaches the main stripping position, locking member 51 is actuated by a cylinder 39 to firmly secure the beam 1' of the cathode plate 1 in position, and locking members 52, 53 are actuated by cylinder 54 and 55 to firmly secure the plate 1 at its lower part. The scraper 50 which is made by precise machining to completely prevent any lateral and vertical deviations is supported by lubricated slide guide 56 and slide head 57 and is actuated by a pushing cylinder 58 through rack 59, pinion 60, gear 61 and rack 62. The scraper is advanced so that its tips are inserted into the gaps which have already been formed between the cathode plate 1 and the deposited metal 36 in the preliminary stripping operation whereby at first the upper portion of the deposited metal is stripped. Next a cylinder 63 disposed to provide for a vertical operational movement is actuated to actuate a rack 68 which is connected with frame 67 through rack 66, pinion 65 and gear 64 associated with the cylinder. The rack 68 moves the scraper 50 downwardly without lateral and vertical deviations which are prevented by the arrangement wherein the scraper is supported on the frame guide 69 by means of slide bearing boxes 70. Consequently the deposited metal is stripped on both faces of the cathode plate 1 at the same time and the stripped metal passes through guide rollers 71 and falls in a container 72 from which it is meanwhile delivered to a stacker stationed under the stripping apparatus.

As mentioned above in detail, the automatic stripping apparatus according to this invention provides a preliminary stripping operation before the cathode plate comes up to the scraper of the main stripping device, whereby the scraper can be inserted into the gap to strip the deposited metal speedily and smoothly. Additionally as the upper and horizontal stripping on one hand and the vertical stripping on the other can be carried out successively by the same scraper, stripping efficiency is extremely increased.

According to the actual operation of the apparatus constructed according to this invention, the time necessary for the treatment of one cathode plate is 8 or 9 seconds.

When the stripping process is finished, the respective devices return to their starting positions and the cathode plate is passed by the feeder 11 to a resetting device 73 at a station (g) at which the movable holder 2 is reset correctly to the cathode plate. Next, the cathode plate 1 is delivered by the feeder 11 to a station (h), transferred to the conveyor 75 by a delivering device 74, and again returned to the electrolytic bath.

When the detector 48 detects, in the above described deposit metal stripping cycle, that the preliminary stripping operation is not satisfactorily carried out, a signal is provided and the cathode plate is not submitted to the following stripping operation but rather is directly discharged for special treatment. Incomplete operation of the preliminary stripping is usually caused by the fact that a sufficient gap is not formed by the movable holder between the deposited metal 36 and cathode plate 1 or for any reason the electrodeposition is not perfect at the portion at which the gap is formed.

As clearly shown in FIG. 10, the tips of the scraper blades have a locus drawn to advance toward the cathode plate 1 for the first time so that sufficient preliminary stripping is obtained if the tips are engaged with even a little of the deposited metal 36.

According to. this invention, as clearly described above, stripping of deposited metal from the cathode plate can very easily and exactly be carried out at necessarily high speed and without damaging the cathode plate.

What is claimed is:

1. Apparatus for stripping deposited metal from a cathode plate in an electrolytic metal winning process comprising: a cathode plate of the type having a cathode holder mounted thereon; means for advancing said cathode plate to a plurality of operating stations, said advancing means including a device movable between an elevated position and a lowered position which slidably reciprocates to a distance corresponding to the distance between any two stations, said device releaseably carrying said cathode plate when in said elevated position and releasing said cathode plate at one of said operating stations when brought to said lowered position, and means for holding said cathode plate at said operating station against lateral and downward move ments; means at one operating station for turning said cathode holder to expose an edge portion between said cathode plate and the deposited metal; preliminary stripping means located at another station, said preliminary stripping means having scraper elements insertable between said cathode plate and the deposited metal at said edge portion to partially separate said deposited metal from said cathode plate; and a main stripping means located at another station, said main stripping means having a scraper blade insertable between the partially separated cathode plate and deposited metal and movable relative to said cathode plate and deposited metal to effect complete separation of said deposited metal from said cathode plate.

2. Apparatus according to claim 1 wherein said main stripping means essentially consists of a single stripping means which comprises an actuating device for advancing said scraper blade in one direction between the partially separated cathode plate and deposited metal, and for subsequently moving said scraper blade in a direction transverse to said one direction to effect complete separation of said deposited metal from said cathode plate, said main stripping means being configured to avoid contact with the surface of said cathode plate while effecting said separation.

3. Apparatus according to claim 1 including a resetting means located at another station, said resetting means being operable to turn said cathode holder to its initial position disposed over an edge portion of said cathode plate.

4. Apparatus according to claim 1 wherein said preliminary stripping means comprises support means pivotally mounting said scraper elements, actuating means for advancing said support means to a position wherein said scraper elements enter into a gap formed between said cathode plate and a turned-up edge portion of said deposited metal, and means for pivoting said scraper elements to initiate partial separation of said deposited metal from said cathode plate.

5. Apparatus according to claim 2 wherein said scraper blades have a longitudinal length substantially equal to the width of said cathode plate.

6. Apparatus according to claim 1 wherein said cathode holder has a beveled surface over which said deposited metal extends, whereby turning of said cathode holder exposes an upturned edge portion on said deposited metal, said upturned edge portion receiving said scraping elements for effecting said partial separatron.

7. Apparatus according to claim 1 including a detector means located between said preliminary stripping means and said main stripping means, said detector means being operable to detect unsuitable cathode plates and malfunctioning of the preliminary stripping operation and to discharge detected cathode plates before the latter reach said final stripping means.

8. Apparatus according to claim 1 wherein said means for turning said cathode holders includes a pivotally mounted arm and means for pivoting said arm, said arm being operable to engage said cathode holder and to pivot the latter from a position where the cathode holder covers said edge portion of said cathode plate to a position where said edge'portion of said cath- 

1. Apparatus for stripping deposited metal from a cathode plate in an electrolytic metal winning process comprising: a cathode plate of the type having a cathode holder mounted thereon; means for advancing said cathode plate to a plurality of operating stations, said advancing means including a device movable between an elevated position and a lowered position which slidably reciprocates to a distance corresponding to the distance between any two stations, said device releaseably carrying said cathode plate when in said elevated position and releasing said cathode plate at one of said operating stations when brought to said lowered position, and means for holding said cathode plate at said operating station against lateral and downward movements; means at one operating station for turning said cathode holder to expose an edge portion between said cathode plate and the deposited metal; preliminary stripping means located at another station, said preliminary stripping means having scraper elements insertable between said cathode plate and the deposited metal at said edge portion to partially separate said deposited metal from said cathode plate; and a main stripping means located at another station, said main stripping means having a scraper blade insertable between the partially separated cathode plate and deposited metal and movable relative to said cathode plate and deposited metal to effect complete separation of said dEposited metal from said cathode plate.
 2. Apparatus according to claim 1 wherein said main stripping means essentially consists of a single stripping means which comprises an actuating device for advancing said scraper blade in one direction between the partially separated cathode plate and deposited metal, and for subsequently moving said scraper blade in a direction transverse to said one direction to effect complete separation of said deposited metal from said cathode plate, said main stripping means being configured to avoid contact with the surface of said cathode plate while effecting said separation.
 3. Apparatus according to claim 1 including a resetting means located at another station, said resetting means being operable to turn said cathode holder to its initial position disposed over an edge portion of said cathode plate.
 4. Apparatus according to claim 1 wherein said preliminary stripping means comprises support means pivotally mounting said scraper elements, actuating means for advancing said support means to a position wherein said scraper elements enter into a gap formed between said cathode plate and a turned-up edge portion of said deposited metal, and means for pivoting said scraper elements to initiate partial separation of said deposited metal from said cathode plate.
 5. Apparatus according to claim 2 wherein said scraper blades have a longitudinal length substantially equal to the width of said cathode plate.
 6. Apparatus according to claim 1 wherein said cathode holder has a beveled surface over which said deposited metal extends, whereby turning of said cathode holder exposes an upturned edge portion on said deposited metal, said upturned edge portion receiving said scraping elements for effecting said partial separation.
 7. Apparatus according to claim 1 including a detector means located between said preliminary stripping means and said main stripping means, said detector means being operable to detect unsuitable cathode plates and malfunctioning of the preliminary stripping operation and to discharge detected cathode plates before the latter reach said final stripping means.
 8. Apparatus according to claim 1 wherein said means for turning said cathode holders includes a pivotally mounted arm and means for pivoting said arm, said arm being operable to engage said cathode holder and to pivot the latter from a position where the cathode holder covers said edge portion of said cathode plate to a position where said edge portion of said cathode plate is exposed. 